期刊文献+

LiFePO_4正极材料及其改性研究进展 被引量:5

Research on LiFePO_4 positive material and its modification
下载PDF
导出
摘要 LiFePO4是最近几年来被广泛关注的锂离子电池正极材料,经过十余年的研究,LiFePO4的合成、改性、应用均取得了实质性进展,该材料已进入实用化阶段。LiFePO4具有比容量高(170 mAh/g),环境相容性好,原料丰富,循环性能好,充放电平台稳定等优点,因此该材料非常适合于对安全性、循环寿命、使用成本等敏感的大型电池应用领域,比如混合动力汽车(HEV)和纯电动汽车(EV)领域。概括了LiFePO4的晶体结构,充放电机理和主要的改性手段,介绍了这种新型锂离子正极材料的研究进展。 LiFePO4 is one of the lithium-ion batteries materials which have attracted wide public concern over the recent years.After more than ten years of research,substantial results have been achieved including the synthesis,modification and application of LiFePO4,and this material has entered the period of practicality production.LiFePO4 is very suitable for large batteries such as HEV and EV which require safety,cyclic life and low cost field because of its high specific capacity(170 mAh/g),good environment compatibility,inexpensive and good cyclic performance.Research progress on LiFePO4 was summarized,including lattice structure,charge and discharge mechanism and modification methods.
出处 《电源技术》 CAS CSCD 北大核心 2013年第1期147-151,共5页 Chinese Journal of Power Sources
关键词 锂离子电池 正极材料 磷酸铁锂 lithium-ion batteries positive materials LiFePO4
  • 相关文献

参考文献25

  • 1PADHI A K,NANJUNDASWAMY K S,GOODENOUGH J B. Phospho-olivines as positive electrode materials for rechargeable lithium batteries[J].Journal of the Electrochemical Society,1997,(4):1189.doi:10.1149/1.1837571. 被引量:1
  • 2GABERSCEK M,DOMINKO R,JAMNIK J. Is small particle size more important than carbon coating?An example study on LiFePO4 cathodes[J].Electrochemistry Communications,2007.2778-2783. 被引量:1
  • 3PROSINIP P,LISI M,ZANE D. Determination of the chemical diffusion coefficient of lithium in LiFePO4[J].Solid State Ionics,2002,(1/2):A45-A51. 被引量:1
  • 4ISLAM M SAIFUL,DRISCOLL DANIEL J,FRISHER C A J. Atomic-scale investigation of defects,dopants,and lithium transport in the LiFePO4 olivine-type battery material[J].Chemistry of Materials,2005.5085-5092. 被引量:1
  • 5PARKA M,ZHANG X C,CHUNG M. A review of conduction phenomena in Li-ion batteries[J].Journal of Power Sources,2010.7904-7929. 被引量:1
  • 6ANDERSSON A S,THOMAS J O. The source of first-cycle capacity loss in LiFePO4[J].Journal of Power Sources,2001.498-502. 被引量:1
  • 7DELMAS C,MACCARIO M,CROGUENNE L. Lithium deintercalation in LiFePO4 nanoparticles via a domino-cascade model[J].Nature Materials,2008,(8):665-671.doi:10.1038/nmat2230. 被引量:1
  • 8LAFFONT L,DELACOURT C,GIBOT P. Study of the LiFePO4/FePO4 two-phase system by high-resolution electron energy loss spectroscopy[J].Chemistry of Materials,2006,(23):5520-5529.doi:10.1021/cm0617182. 被引量:1
  • 9PROSINI P P. Modeling the voltage profile for LiFePO4[J].Journal of the Electrochemical Society,2005,(10):A1925-A1929. 被引量:1
  • 10RAVET N,GOODENOUGH J B,BESNER S. Improved iron based cathode material[J].Journal of the Electrochemical Society,1999.172. 被引量:1

同被引文献45

  • 1钟泽钦,孔令涌,黄少真,尚伟丽,张瑞芳,陈玲震.超导电碳基涂层铝箔制备及对高能量磷酸铁锂电池的影响[J].化工新型材料,2020,48(1):189-192. 被引量:4
  • 2倪江锋,苏光耀,周恒辉,陈继涛.锂离子电池正极材料LiMPO_4的研究进展[J].化学进展,2004,16(4):554-560. 被引量:46
  • 3GOODENOUGH J B, PADHI A, NANJUNDASWAMY K S,et al.Cathode materials for secondary (rechargeable) lithium batteries:WO, 97/40541[P]. 1997-10-30. 被引量:1
  • 4ARMAND M, RAVET N,BENSNER S, et al. New electrode mate-rials with high surface conductivity: CA, 2270771 [P].2000-10-30. 被引量:1
  • 5BARKER J, SAIDI M Y. Lithium-based electrochemically activematerials and preparation thereof: WO, 01/54212[P].2001~07-26. 被引量:1
  • 6BARKER J, SAIDI M Y, SWOYER J L. Lithium metal fluorophos-phates materials and preparation thereof: WO, 01/84655 [P].2001-11-08. 被引量:1
  • 7YAMAHIRA T, YAMADA A. Positive electrode and non-aqueouselectrolyte cell: CA,2344981 [P].2001 -10-25. 被引量:1
  • 8BARKER J, SAIDI M Y, SWOYER J L. Preparation of lithium-con-taining materials: WO, 01 /53198[P].2001 -07-26. 被引量:1
  • 9张中太,卢俊彪,唐子龙,等.一种橄榄石结构的多晶1^?汗04粉体制备方法:CN, 1410349[P].2003-04-16. 被引量:1
  • 10张中太,卢俊彪,唐子龙,等.反相插锂法制备多晶LiFeP04纳米粉体材料:CN, 1469499[P].2004-01-21. 被引量:1

引证文献5

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部