摘要
以尿素为螯合剂、十二烷基硫酸钠(K12)为表面活性剂,采用水热法合成YPO4:Tb3+,Ce3+微米球。利用SEM、XRD、光致发光光谱、激发谱、荧光衰减曲线等分析手段对YPO4:Tb3+,Ce3+微米球的形貌、相结构、光学特性及相关激发与发射机制进行研究。结果表明:合成的YPO4:Tb3+,Ce3+微米球荧光颗粒形貌规则,呈纯净四方相。共掺Ce3+离子使得微米球的544 nm绿光发射的相对强度得到有效调制;对荧光衰减谱的双参数拟合,证实Ce3+与Tb3+之间能量传递的存在。
The YPO4:Tb3+,Ce3+ microspheres were synthesized through hydrothermal method by using urea as chelatingagent and sodium dodecylsulfate(K12) as surfactant.The morphology,phase structure,optical property and relative excitation and emission mechanism of YPO4: Tb3+,Ce3+ microspheres were characterized by scanning electron microscopy(SEM),X-ray diffractometry(XRD),photoluminescence(PL) excitation spectra and decay spectra technique.The results reveal that the synthesized microspheres show uniform morphologies and pure tetragonal phase of YPO4.The relative intensity of 544 nm green emission of Tb3+ to other emission bands can be efficiently tuned by codoping Ce3+.Finally,the energy transfer was confirmed to occur between Ce3+ and Tb3+ when the decay spectra of Tb3+ is fitted by a double-exponential function by fitting the decay spectra.
出处
《中国有色金属学报》
EI
CAS
CSCD
北大核心
2012年第12期3562-3567,共6页
The Chinese Journal of Nonferrous Metals
基金
国家自然科学基金资助项目(51175172)
国家自然科学基金重点项目(51174088
51134005)
湖南省自然科学基金资助项目(10JJ6008)
湖南科技大学研究生创新基金资助项目(S100126)
关键词
Ce3+
TB3+
荧光颗粒
敏化
交叉弛豫
双参数拟合
衰减曲线
Ce3+
Tb3+
fluorescent particles
sensitization
cross-relaxation
double-exponential fitting
decay-curve
