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PANI/TiO_2复合材料的合成条件研究及可见光催化性能 被引量:2

Synthesis conditions of PANI/TiO_2 composite materials and visible light photocatalytic activity
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摘要 采用原位化学氧化聚合法制备了一系列不同酸掺杂和不同氧化剂用量的PANI/TiO2复合光催化材料,利用IR对其结构进行表征,并研究了该系列光催化材料在可见光下对甲基红的降解情况。通过研究表明当苯胺与TiO2的质量比为5:1,AN与APS摩尔比为2:1时,可见光催化活性较好;硫酸掺杂的PANI/TiO2可见光催化活性较好。 A series of PANI/TiO2 photocatalyst powders doped with different acid and different amount of oxidant were successfully prepared by in situ chemical oxidation polymerization, and characterized by Infrared Ray. Degradation of organic dye methyl red under Visible light catalyzed by the prepared catalyst was studied. Results showed that when the mass ratio of aniline(AN) to titania(TiO2) was 5 : 1,the molar ratio of AN to APS was 2 : 1,the catalyst was of good photocatalytic activity. It was also found that the PANI/TiO2 composite photocatalysis material doped with sulfuric acid had stronger photocatalytic activity.
出处 《化工新型材料》 CAS CSCD 北大核心 2012年第12期58-60,共3页 New Chemical Materials
基金 中央高校基本科研业务费专项资金资助(2011D11304) 科技部公益性行业科研专项(GYHY200706036) 国家自然科学基金资助项目(50874032) 研究生课程建设资助项目(Y201002011) 上海市重点学科建设资助项目(B604)
关键词 聚苯胺 二氧化钛 可见光 合成 光催化 polyaniline, titania, visible light, synthesis, photocatalysis
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  • 1Su Shijian , Kuramoto N. Processable polyaniline titanium diox- ide nanocomposites : effect of titanium dioxide on the conductiv- ity [J]. Synthetic Metals ,2000 ,114:147-153. 被引量:1
  • 2Bian Chaoqing, Yu Yijun, Xue Gi. Synthesis of conducting poly- aniline/TiO2 composite nano? bres by one-step in situ polymer ization method[J]. Journal of Applied Polymer Science,2006. 被引量:1
  • 3Li Qiaoling,et al. Photocatalysis and wave-absorbing properties of polyaniline/TiO2 microbelts composite by in situ polymeriza tion method[J]. Applied Surface Science,257(2010) 944 -948. 被引量:1
  • 4Zhang Liuxue, Liu Peng, Su Zhixing. Preparation of PANLTiO2 nanocomposites and their solid-phase photocatalytic degradation [J]. Polymer Degradation and Stability,2006. 被引量:1
  • 5曾幸荣,龚克成.聚苯胺的掺杂及其性能的研究[J].高分子材料科学与工程,1991,7(6):73-77. 被引量:18
  • 6Stejskal J,Kratochvil P,Jenkins A D. The formation of polyan- line and the nature of its structures [J . Polymer Communica tion, 1996,37(2) : 367-369. 被引量:1

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共引文献17

同被引文献26

  • 1Kansal S K, Singh M, Sud D. Studies on Photodegradation of Two Commercial Dyes in Aqueous Phase Using Different Photocatalysts[ J]. Journalof hazardous materials ,2007,3 ( 141 ) :581-590. 被引量:1
  • 2Faisal M, Tariq M A, Muneer M. Photocatalysed Degradation of Two Selected Dyes in UV-irradiated Aqueous Suspensions of Titania[ J ]. Dyes and Pigments,2007,72 (2) :233-239. 被引量:1
  • 3Teruhisa O, Miyako A, Tsutomu U, et al. Preparation of S-doped TiO2 Photocatalysts and Their Photocatalytic Activities under Visible Light[ J ]. Applied catalysis A General,2004,265 ( 1 ) : 115-121. 被引量:1
  • 4Asahi R, Morikawa T, Ohwaki T, et al. Visible-light Photocatalysis in Nitrogen-doped Titaniumoxides [ J ]. Science, 2001,293 ( 5529 ) : 269 -271. 被引量:1
  • 5Wu N L, Lee M S. Enhanced TiO2 Photocatalysis by Cu in Hydrogen Production from Aqueous Methanol Solution[J]. International Journal of Hydrogen Energy,2004,29 ( 15 ) : 1601-1605. 被引量:1
  • 6Yao K S, Wang D Y, Chang C Y, et al. Photocatalytic Disinfection of Phytopathogenic Bacteria by Dye-sensitized TiO2 Thin Film Activated by Visible Light[ J]. Surface Coating Technology,2007,202 (1-3) :1329-1332. 被引量:1
  • 7Wang D S, Wang Y H, Li X Y, et al. Sunlight Photocatalytic Activity of Polypyrrole-TiO2 Nanocomposites Prepared by in Situ Method [ J ]. Catalysis Communications ,2008,3-4(81 ) :276-273. 被引量:1
  • 8Wang D S, Zhang J, Luo Q Z, et al. Characterization and Photocatalytic Activity of Poly(3-hexylthiophene)-modified TiO2 for Degradation of Methyl Orange under Visible Light [ J ]. Journal of Hazardous Materials,2009,169 ( 1-3 ) :546-550. 被引量:1
  • 9Hebestret N, Hofmsnn J, Rammel T U, et al. Physical and Electrochemical Characterization of Nanocomposites from Polythiophene and Titanium Dioxide[ J. Electrochemica Acta ,2003,48 (4) : 1779-1788. 被引量:1
  • 10Muktha B, Mahanta D, Patil S, et al, Synthesis and Photocatalytic Activity of poly ( 3-hexyhhiophene )/TiO2 Composites [ J ]. Journal of Solid State Chemistry,2007,180(4) :2986-2989. 被引量:1

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