摘要
利用水热合成制备了一个新的吡啶基多羧酸钇配合物YL(HL).2H2O(1)(H2L=5-((吡啶基-3-亚甲基)氨基)间苯二甲酸)。利用元素分析及X-射线单晶衍射对其进行了表征。结构分析结果表明标题化合物1属于三斜晶系,P1空间群,晶胞参数为a=1.015 35(11)nm,b=1.083 33(12)nm,c=1.287 40(14)nm,α=70.9430(10)°,β=127.689(3)°,γ=84.0680(10)°,晶胞体积V=1.317 0(2)nm3,Z=2,Dc=1.680 g.cm-3,F(000)=680,μ=2.284 cm-1,R=0.056 2,wR=0.1600。在化合物1中,每个Y的配位环境为八配位的反四棱柱配位构型。该配合物的二维结构是少见的(42.6)(42.67.8)层状拓扑。我们对配合物1的粉末衍射数据和热重分析也进行的讨论。
By using hydrothermal method, the reaction with yttrium nitrate led to the formation of a novel yttrium 5-（（pyridine-3-ylmethyl）amino）isophthalic acid （H2L） complex, namely, YL（HL）· 2H2O （1）, with interesting two-dimensional （2D） topology. The title complex was characterized by elemental analysis and IR spectroscopy and its structure was determined by single crystal X-ray structural analysis. The result of structural analysis shows that the 1 crystallizes in triclinic, space group P1 with α=1.015 35（11） nm, b=1.083 33（12） nm, c=1.287 40（14） nm, α=70.9430（10）°, β=127.689（3）°, y=84.0680（10）°, V=1.317 0（2） nm3, Z=2, Dc=1.680 g·cm^-3, F（000）=680,μ=2.284 cm-1, R=0.056 2, wR=0.160 0. The Y（Ⅲ）atoms was eight-coordinated with carboxylate O atoms in square- antiprismatic geometry. In complex 1, the 2D layer comprised of μ2/μ3ligands and 5-connected Y（Ⅲ） centers is rare example of 2-nodal net of （42.6）（42.67.8） topology. The XPRD and TGA analysis were also investigated. CCDC： 864386.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2012年第11期2407-2412,共6页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.20901004,20801025)资助项目
关键词
晶体结构
钇配合物
拓扑
羧酸配体
crystal structure
Y（Ⅲ） complex
topochemistry
carboxylate ligand
