期刊文献+

丙环唑在香蕉及土壤中的残留量测定 被引量:4

Residue Determination of Propiconazole in Banana and Soil
下载PDF
导出
摘要 研究了丙环唑在香蕉及土壤中的残留降解情况,评价其施用于香蕉后的安全性。采用GC–NPD进行定量检测,丙环唑在香蕉全蕉中的平均回收率为100.6%~108.0%;在香蕉蕉肉中的平均回收率为71.0%~96.2%;在土壤中的平均回收率为97.3%~110.4%。研究结果表明,丙环唑在香蕉全蕉中比在土壤中消解快,2010年其在香蕉全蕉和土壤中消解半衰期分别为11.4 d和17.5 d,2011年分别为15.3 d和24.3 d。在香蕉上按照推荐剂量施药3次,采收期距最后一次施药42 d,香蕉蕉肉中丙环唑残留量小于0.1 mg/kg,低于GB 2763—2005规定的最大残留限量(MRL)0.1 mg/kg。 The residues and degradation of propiconazole in banana and soil were studied to evaluate its security.Propiconazole was determined by GC-NPD.Its average recoveries were 100.6%-108.0% in the whole fruit of banana,71.0%-96.2% in banana flesh and 97.3%-110.4% in soil.The half-lives of propiconazole in banana whole fruit and soil were 11.4 d and 17.5 d in 2010,15.3 d and 24.3 d in 2011,respectively.When banana was treated with propiconazole at recommended dose for 3 times,on the harvest day which was the 42th day after the last application,the final residue of propiconazole in banana flesh was below 0.1 mg/kg which was the maximum residue limit(MRL) established in GB 2763-2005.
出处 《现代农药》 CAS 2012年第5期44-47,共4页 MODERN AGROCHEMICALS
基金 海南省自然基金(211018)
关键词 丙环唑 GC–NPD 残留量 香蕉 土壤 propiconazole GC-NPD residue banana soil
  • 相关文献

参考文献9

二级参考文献18

共引文献104

同被引文献44

  • 1顾晓军,田素芬.农药与癌症[J].世界科技研究与发展,2005,27(2):47-52. 被引量:6
  • 2Andreia P S, Sandra S M, Gilberto M. Specific adsorption of propiconazole and humic acid on Pt and PtO films[J]. Electrochimica Acta, 2009, 54: 6 896 - 6 907. 被引量:1
  • 3Chen P J, Moore T, Nesnow S. Cytotoxic effects of propiconazole and its metabolites in mouse and human hepatoma cells and-primary mouse hepatocytes[J]. Toxicology in Vitro, 2008. 22(6):1476-1483. 被引量:1
  • 4Daniel S L, Hartman G L, Wagner E D, et al. Mammalian Cell Cytotoxicity Analysis of Soybean Rust Fungicides [J]. Bull Environ Contam Toxicol, 2007, 78:474-478. 被引量:1
  • 5Andreia P S, Sandra SM. Gilberto M. Specific adsorption of propiconazole and humic acid on Pt and PtO films[J]. Electrochimica Acta. 2009, 54: 6 896 - 6 907. 被引量:1
  • 6Li Z H, Ziabek V. Li P. et al. Biochemical and physiological responses in liver and muscle of rainbow trout after long-term exposure to propiconazole[J]. Ecotoxicology and Environmental Safety, 2010, 73( 6):1 391-1 396. 被引量:1
  • 7Soetaert A. Moens L N, Van der Ven K, et al. Molecular impact of propiconazole on Daphnia magna using a repro- duct ion -related cDNA array[]J. Comparative Biochemistry and Physiology, Part C, 2006, 142: 66 -76. 被引量:1
  • 8Kast - Hutcheson K, Rider C V, LeBlanc G A. The fungicide propiconazole interferes with embryonic development of the crustacean Daphnia magna. Environ[JJ. Toxicol Chern , 2001, 20: 502- 509. 被引量:1
  • 9Stephen N, Rachel D G, Guy L, et al. Propicpropiconazole increases reactive oxygen species levels in mouse hepatic cells in culture and in mouse liver by a cytochrome P450 enzyme mediated process [J]. Chemica Biological Interac?tions, 2011,194:79-89. 被引量:1
  • 10Ross J A, Leavitt S A, Schmid J E, et al. Quantitative changes in ndogenous DNA adducts correlate with conazole in vivo mutagenicity and tumorigenicity[JJ. Mutagenesis, 2012. 被引量:1

引证文献4

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部