摘要
利用DSC技术研究了5种N,N’-二四唑胺过渡金属配合物MBTA(H2O)n(M=Mn、Co,n=4;M=Ni,n=3;M=Zn,n=3.5;M=Pb,n=2;BTA2-=N,N’-二四唑离子)对RDX和HMX热分解行为的影响,从分解峰温、热爆炸临界温度等特征参数评价了配合物对RDX和HMX热分解行为的影响效果。
The effects on the thermal decomposition behavior of five transitions metal N,N'-bis-( 1 (2)H-tetrazol-5-yl-) amine complexes M (BTA) ( H2O), ( M = Mn, Co, n = 4 ; M = Ni, n = 3 ; M = Zn, n = 3.5 ; M = Pb, n = 2 ; BTA2 - = N, N' -bis- ( 1 (2) H-tetrazol-5-yl-) amine ion) act on RDX and HMX were investi- gated with DSC technique. The experimental results were evaluated from characteristic parameters, such as maximum decomposition peak temperature, critical temoerature of thermal explosion.
出处
《应用化工》
CAS
CSCD
2012年第9期1563-1566,共4页
Applied Chemical Industry
基金
陕西省教育厅项目(11JK0577)
关键词
含能配合物
燃速催化剂
热分解
energetic complex
combustion catalyst
thermal decomposition