摘要
采用金属负载型阳离子交换树脂作催化剂,乙醇和丁二酸酐为原料,对琥珀酸单乙酯的合成进行了研究,确定了最佳工艺条件:原料摩尔比n(乙醇)/n(丁二酸酐)=1.3:1,催化剂用量占丁二酸酐用量的15%,反应温度85℃,反应时间90min,乙酸正丁酯的产率达到93%以上。
Mono-ethyl succinate was synthesized with ethanol and succinic anhydride catalyzed by metal-loaded cation exchange resin. The influence factors and the optimum process conditions were determined： mole ratio n（ethanol ）/n（succinic anhydride） =1.3 ： 1, metal-loaded cation exchange resin was 15% of the amount of succinic anhydride, temperature 85 ℃ and reaction time 90 minutes. Under these conditions, the yield of mono-ethyl succinate was above 93 %.
出处
《化工技术与开发》
CAS
2012年第8期7-10,共4页
Technology & Development of Chemical Industry
关键词
琥珀酸单乙酯
阳离子交换树脂
乙醇
丁二酸酐
最佳工艺条件
mono-ethyl succinate
cation exchange resin
ethanol
succinic anhydride
optimum process condition
