摘要
在聚乙烯吡咯烷酮的辅助下,采用多元醇法制备了不同铜/锌摩尔比的硫化亚铜/四针状氧化锌晶须纳米复合材料,并利用X射线衍射、场发射扫描电镜、X射线光电子能谱和紫外-可见漫反射光谱对样品进行了表征.结果表明,在紫外光照射下,样品对甲基橙的光降解效率优于纯ZnO晶须.在铜/锌摩尔比低于4%时,样品的光催化性能随着铜/锌摩尔比增加而增加,但随着铜/锌摩尔比的继续增加,样品的光催化性能下降.此外,还采用周期实验来评价催化剂的稳定性.结果表明,该催化剂具有优异的光催化稳定性.
Nanocomposites of tetrapod-like ZnO whisker（T-ZnOw） with loaded Cu2S were synthesized with different Cu/Zn molar ratios with the assistant of poly（vinyl pyrrolidone）（PVP） by the polyol process.The composite samples were characterized by X-ray diffraction,field emission scanning electron microscopy,X-ray photoelectron spectroscopy,and UV-visible diffuse reflectance spectroscopy.The photocatalytic activities for the Cu2S/T-ZnOw nanocomposites increased with Cu/Zn molar ratio up to 4%,and then decreased with further increase of the Cu/Zn molar ratio up to 10%.The Cu2S/T-ZnOw nanocomposites exhibited higher activity than T-ZnOw for the photocatalytic degradation of methyl orange.Recycling experiments were also performed.The photocatalytic activity of the photocatalyst showed no decrease after three cycles,which demonstrated that the Cu2S/T-ZnOw photocatalyst had excellent stability.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2012年第5期802-807,共6页
基金
国家高技术研究发展计划(863计划,2009AA03Z427)
四川省科学基金(2006z02-006-3)~~
关键词
氧化锌
硫化亚铜
多元醇法
光催化性能
甲基橙
zinc oxide
copper sulphide
polyol method
photocatalytic performance
methyl orange
