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A Sustainable Synthesis of 2-Benzoxazyl and 2-Benzothiazyl Ketones from Alkynyl Bromides and 2-Amino(thio)phenols Promoted by a Recyclable Catalytic System

A Sustainable Synthesis of 2-Benzoxazyl and 2-Benzothiazyl Ketones from Alkynyl Bromides and 2-Amino(thio)phenols Promoted by a Recyclable Catalytic System
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摘要 An environmentally and economically sustainable synthesis of 2-benzoxazyl ketones and 2-benzothiazyl ke- tones through FeC13·6H2O catalyzed tandem reactions of alkynyl bromides with 2-amino(thio)phenols in [bmim]BF4 has been developed. Remarkable advantages of this new synthetic strategy include high efficiency, readily available starting materials, and recyclable catalyst and reaction medium. An environmentally and economically sustainable synthesis of 2-benzoxazyl ketones and 2-benzothiazyl ke- tones through FeC13·6H2O catalyzed tandem reactions of alkynyl bromides with 2-amino(thio)phenols in [bmim]BF4 has been developed. Remarkable advantages of this new synthetic strategy include high efficiency, readily available starting materials, and recyclable catalyst and reaction medium.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第4期992-996,共5页 中国化学(英文版)
关键词 2-benzoxazyl ketone 2-benzothiazyl ketone alkynyl bromide FeCl3·6H2O ionic liquid 2-benzoxazyl ketone, 2-benzothiazyl ketone, alkynyl bromide, FeCl3·6H2O, ionic liquid
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