摘要
金属配位聚合物是一种新型功能性分子材料,近年来得到科学家的普遍关注。主要对配位聚合物在金属-氧簇化合物、三维开放式网络、缠结网络的研究热点进行了综述,综述了金属配位聚合物研究的重要性和国内外金属配位聚合物的研究工作。首先,对金属-氧簇化合物的各个类型分别进行介绍;其次,叙说了三维开放式网络的刚性多孔网络和柔性多孔网络;最后,介绍了缠结网络中的互穿网络和自穿网络;并对其发展前景作出了展望。
As a new type of potential functional materials,the metal coordination polymer has attracted many attentions in the last few years.The focuses in metal-oxygen clusters,three-dimensional of the open network,entanglement network of coordination compounds are reviewed.The importance of research on metal coordination polymer is presented,as well as the studies on coordination polymer at home and abroad.Firstly,all kinds of metal- oxygen clusters are introduced;secondly,the rigid and flexible porous network of three-dimensional of the open network is described;finally,the inter- penetration and self-penetration network of entanglement network are introduced;the future development in this field is also briefly mentioned.
出处
《化学与粘合》
CAS
2012年第2期65-66,70,共3页
Chemistry and Adhesion
基金
陕西省重点实验室重点科学研究项目(编号:2010JS069)
陕西省科技厅资助项目(编号:07B24
2010JK409)
关键词
配位聚合物
金属-氧簇化合物
三维开放式网络
缠结网络
Coordination pllymer,metal-oxygen clusters
three-dimensional of the open network
entangtlement network