期刊文献+

Nano-confined ammonia borane for chemical hydrogen storage 被引量:2

Nano-confined ammonia borane for chemical hydrogen storage
原文传递
导出
摘要 There is a great demand for a sufficient and sustainable energy supply. Hence, the search for applicable hydrogen storage materials is extremely important owing to the diversified merits of hydrogen energy. In this regard, ammonia borane (NH3BH3, AB) containing 19.6wt-% hydrogen has been considered as a promising material for hydrogen storage applications to realize the "hydrogen economy", but with limits from slow kinetics of hydrogen release and by-product of trace gases such as ammonia and borazine. In this review, we introduce the recent research on AB, regarding to the nanoconfinement effect on improving the kinetics at a relatively low temperature and the prevention/reduction of undesirable gas formation. There is a great demand for a sufficient and sustainable energy supply. Hence, the search for applicable hydrogen storage materials is extremely important owing to the diversified merits of hydrogen energy. In this regard, ammonia borane (NH3BH3, AB) containing 19.6wt-% hydrogen has been considered as a promising material for hydrogen storage applications to realize the "hydrogen economy", but with limits from slow kinetics of hydrogen release and by-product of trace gases such as ammonia and borazine. In this review, we introduce the recent research on AB, regarding to the nanoconfinement effect on improving the kinetics at a relatively low temperature and the prevention/reduction of undesirable gas formation.
出处 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2012年第1期27-33,共7页 化学科学与工程前沿(英文版)
关键词 ammonia borane hydrogen storage ammonia borane, hydrogen storage
  • 相关文献

参考文献49

  • 1Schlapbach L,Züttel A. Hydrogen-storage materials for mobile applications[J].Nature,2001,(6861):353-358. 被引量:1
  • 2Baitalow F,Wolfa G,Grolier J P E,Dane F Randzio S L. Thermal decomposition of ammonia-borane under pressures up to 600 bar[J].Thermochimica Acta,2006,(02):121-125. 被引量:1
  • 3Klooster W T,Koetzle T F,Siegbahn P E M,Richardson T B Crabtree R H. Study of the N-H… H-B dihydrogen bond including the crystal structure of BH3NH3 by neutron diffraction[J].Journal of the American Chemical Society,1999,(27):6337-6343. 被引量:1
  • 4Umegaki T,Yan J M,Zhang X B,Shioyama H Kuriyama N Xu Q. Boron-and nitrogen-based chemical hydrogen storage materials[J].International Journal of Hydrogen Energy,2009,(05):2303-2311.doi:10.1016/j.ijhydene.2009.01.002. 被引量:1
  • 5Smythe N C,Gordon J C. Ammonia borane as a hydrogen carrier:dehydrogenation and regeneration[J].European Journal of Inorganic Chemistry,2010,(04):509-521. 被引量:1
  • 6Rassat S D,Aardahl C L,Autrey T,Smith R S. Thermal stability of ammonia borane:a case study for exothermic hydrogen storage materials[J].Energy and Fuels,2010,(04):2596-2606. 被引量:1
  • 7Shore S G,Parry R W. The crystalline compound ammonia-borane,NH3BH3[J].Journal of the American Chemical Society,1955,(22):6084-6085. 被引量:1
  • 8Shore S G,Parry R W. Chemical evidence for the structure of the “diammoniate of diborane”.Ⅱ.The preparation of ammonia-borane[J].Journal of the American Chemical Society,1958,(01):8-12. 被引量:1
  • 9Stephens F H,Pons V,Tom Baker R. Ammonia-borane:the hydrogen source par excellence[J].Dalton Transactions,2007,(25):2613-2626. 被引量:1
  • 10Staubitz A,Robertson A P M,Manners I. Ammonia-borane and related compounds as dihydrogen sources[J].Chemical Reviews,2010,(07):4079-4124.doi:10.1021/cr100088b. 被引量:1

引证文献2

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部