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水溶液中一步合成二吡咯甲烷类化合物 被引量:3

One-Step Synthesis of Dipyrromethanes in Water
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摘要 在水相中,以磷钨酸为催化剂,吡咯与羰基化合物为底物,室温下一步合成了二吡咯甲烷类化合物,反应产物纯度高,无需进一步纯化.该方法具有明显的环境友好、产率高和操作过程简便的优点. A novel and non-conventional synthesis of meso-substitued dipyrromethanes under the catalysis of H3PW12O40 in water at room temperature is described in this paper.The reactions were performed under mild conditions,affording various dipyrrometnanes in good to excellent yields and high purity.
出处 《有机化学》 SCIE CAS CSCD 北大核心 2012年第3期616-620,共5页 Chinese Journal of Organic Chemistry
关键词 二吡咯甲烷 吡咯 羰基化合物 绿色化学 dipyrromethane pyrrole carbonyl compound water green chemistry
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