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硫酸铵存在下碘化钾-乙醇体系萃取分离镉 被引量:32

Extraction Separation of Cadmium by KI-Ethanol in the Presence of (NH_4)_2SO_4
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摘要 A study on liquid liquid extraction of cadmium based on KI ethanol in the presence of ammonium sulphate has been performed. It shows that the charged complex compound CdI 2- 4 could be easily extracted into the ethanol phase. Common ions such as Fe 3+ , Co 2+ , Ni 2+ , Mn 2+ , Zn 2+ , Al 3+ and Cr 3+ would not be extracted into the ethanol phase and Cd 2+ could be separated completely from them by mixture of 3.0 g (NH 4) 2SO 4 and 0.2 g KI in 10.0 mL 30%(volume fraction) ethanol solution at pH=1~5. A study on liquid liquid extraction of cadmium based on KI ethanol in the presence of ammonium sulphate has been performed. It shows that the charged complex compound CdI 2- 4 could be easily extracted into the ethanol phase. Common ions such as Fe 3+ , Co 2+ , Ni 2+ , Mn 2+ , Zn 2+ , Al 3+ and Cr 3+ would not be extracted into the ethanol phase and Cd 2+ could be separated completely from them by mixture of 3.0 g (NH 4) 2SO 4 and 0.2 g KI in 10.0 mL 30%(volume fraction) ethanol solution at pH=1~5.
出处 《应用化学》 CAS CSCD 北大核心 2000年第1期69-71,共3页 Chinese Journal of Applied Chemistry
基金 河南省科委 省教委自然科学基金
关键词 萃取分离 乙醇 碘化钾 硫酸铵 cadmium,extraction separation,ethanol,potassium iodide
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