摘要
以均苯四甲酸酐、邻苯二甲酸酐、氯化亚铁为起始化合物,在钼酸铵作用下,经亲核加成反应生成对二甲酸酐酞菁亚铁前驱体,以化合物对二甲酸酐酞菁亚铁为前驱体,在钼酸铵的作用下发生多环合四聚反应,得到均聚型线性(一维)聚合酞菁亚铁,分别用紫外可见光谱、红外光谱及X射线衍射确认了聚合物的结构。
The iron(Ⅱ) phthalocyanine derivative(AFePc) is synthesized in the catalysis of ammonium molybdate, with pyromellitic anhydride,o-phthalic anhydride and iron(Ⅱ) chloride as starting materials.Then linear iron(Ⅱ) polyphthalocyanine is obtainted by several cyclization tctramerization reaction in the catalysis of ammonium molybdate,with AFePc as precursor.Ultraviolet-visible(UV-vis) spectrophotometer,Fourier transform infrared spectrometer(FT-IR) and X-ray diffraction confirm the structure of polyphthalocyanine.
出处
《精细与专用化学品》
CAS
2012年第1期26-30,共5页
Fine and Specialty Chemicals
关键词
聚合酞菁亚铁
对二甲酸酐酞菁亚铁
邻苯二甲酸酐
iron(Ⅱ) polyphthalocyanine
alignment anhydride iron(Ⅱ) phalocyanine
o-phthalic anhydride