摘要
The batch photodegradation reactor was used to investigate the influence of the common coexisting substances in wastewater,such as H+,anions (HCO3-,Cl-and NO3-) and organic compounds (methanol and bisphenol A),on the photodegradation behaviors of EE2 in the UV/H2O2 process.The results indicated that the addition of coexisting substances can influence the photodegradation behaviors of EE2 and it also follows the first-order kinetics.The acidic (pH 2-4) and alkaline (pH 10-12) medium benefit the photodegradation of EE2,but the photodegradation rate constant of EE2 keeps almost constant in the pH value of 4-10.The addition of anions,such as HCO3-,Cl-and NO3-,can inhibit the photodegradation of EE2,and the rate constant has a negative linear relationship with the concentration of the anions.However,the reduction degrees vary with the anions kinds,and the inhibition effect of the three anions is in the order of HCO3->NO3->Cl-.Addition of 5 mg/L methanol and bisphenol A can reduce the photodegradation rate constant of EE2by 84.31% and 72%,respectively.By comparison,the retardant effect of methanol is much more evident.In the studied concentrations range,the photodegradation rate constant of EE2 is the unary quadratic function of the organic compounds concentrations.
The batch photodegradation reactor was used to investigate the influence of the common coexisting substances in wastewater, such as H2 , anions （HCO3 - , Cl- and NO3 - ） and organic compounds （methanol and bisphenol A） , on the photodegradation behaviors of EE2 in the UV/H2O2 process. The results indicated that the addition of coexisting substances can influence the photodegradation behaviors of EE2 and it also follows the first-order kinetics. The acidic （pH 2 -4） and alkaline （pH 10 - 12） medium benefit the photodegradation of EEz, but the photodegradation rate constant of EE2 keeps almost constant in the pH value of 4 - 10. The ad- dition of anions, such as HCO3 - , C1- and NO3 - , can inhibit the photodegradation of EE2, and the rate con- stant has a negative linear relationship with the concentration of the anions. However, the reduction degrees va- ry with the anions kinds, and the inhibition effect of the three anions is in the order of HCO3 - 〉 NO3 - 〉 C1 -. Addition of 5 mg/L methanol and bisphenol A can reduce the photodegradation rate constant of EE2 by 84. 31% and 72% , respectively. By comparison, the retardant effect of methanol is much more evident. In the studied concentrations range, the photodegradation rate constant of EE2 is the unary quadratic function of the organic compounds concentrations.
基金
Sponsored by the Key Project of National Science Foundation of China (Grant NO.50638020)
the National High Technology Research and Development Program of China (Grant No.2007AA06A411)
the State Key Laboratory of Urban Water Resource & Environment (Grant No.2009TS04)
