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Study on the Separation of Rare Earths with the Method of H(DEHP)-Extraction Chromatography

Study on the Separation of Rare Earths with the Method of H(DEHP)-Extraction Chromatography
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摘要 Separation of rare earths was investigated by extraction chromatography where H(DEHP)was used as a stationary phase,while HCl and H_2SO_4 solutions as a mobile phase.The average separation fac- tors of rare earths,β_(HCl) and β_(H_2SO_4),are 3.79 and 4.57.respectively.The β_(La)^(Ce) in HCl and H_2SO_4 systems are as high as 28.5 and 26.3,respectively.The elution acidity in the study can be down to one tenth and one four- teenth of that in HEH(EHP)system. Separation of rare earths was investigated by extraction chromatography where H(DEHP)was used as a stationary phase,while HCl and H_2SO_4 solutions as a mobile phase.The average separation fac- tors of rare earths,β_(HCl) and β_(H_2SO_4),are 3.79 and 4.57.respectively.The β_(La)^(Ce) in HCl and H_2SO_4 systems are as high as 28.5 and 26.3,respectively.The elution acidity in the study can be down to one tenth and one four- teenth of that in HEH(EHP)system.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 1993年第1期58-62,共5页 稀土学报(英文版)
关键词 Rare earths Di-(2-Ethylhexyl)phosphoric acid Extraction chromatography Rare earths Di-(2-Ethylhexyl)phosphoric acid Extraction chromatography
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