THE LINEAR CORRELATIONS BETWEEN ELECTRONIC TRANSITION ENERGY AND HAMMETT CONSTANTS FOR THE SUBSTITUTED PORPHYRIN-LIKE MACROCYCLE

THE LINEAR CORRELATIONS BETWEEN ELECTRONIC TRANSITION ENERGY AND HAMMETT CONSTANTS FOR THE SUBSTITUTED PORPHYRIN-LIKE MACROCYCLE

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摘要 The properties of absorption spectra are presented and the linear correlations of Hammett constants with the 0-0 transition energy(E_(o,o))of S_←S_o, and the ratios of oscillator strength(f/f)are used to probe the interactions betwee π-electron of aromatic maerocycles or metal ion of complexes with the sub- stituents on β-position of benzene ring for porphyrin-like maerocyclic compounds. The properties of absorption spectra are presented and the linear correlations of Hammett constants with the 0-0 transition energy(E_(o,o))of S_←S_o, and the ratios of oscillator strength(f/f)are used to probe the interactions betwee π-electron of aromatic maerocycles or metal ion of complexes with the sub- stituents on β-position of benzene ring for porphyrin-like maerocyclic compounds.

作者 Shi Ming DONG Duo Yuan WANG Institute of Photographic Chemistry,Academia Sinica,Beijing 100101

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第3期243-246,共4页 中国化学快报（英文版）

基金 This work is supported by NSFC.

关键词 TXP Cd CI THE LINEAR CORRELATIONS BETWEEN ELECTRONIC TRANSITION ENERGY AND HAMMETT CONSTANTS FOR THE SUBSTITUTED PORPHYRIN-LIKE MACROCYCLE

分类号 O6 [理学—化学]

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1Liang ZHAO,Guang Li HU,Fu Xin XIE,Zhi Qiang XU and Shi Sheng NI(Department of Chemistry, Anhui University, Hefei 230039)(State Key Lab. of Coord. Chem., Nanjing Univ., Nanjing 210093).A　NEW　CHEMICAL　OSCILLATOR　WITH　A　MACROCYCLIC　COPPER（Ⅱ）　COMPLEX　AS　THE　CATALYST　AND　MALIC　ACID　AS　THE　SUBSTRATE[J].Chinese Chemical Letters,1996,7(6):579-580.
2The Synthesis and Structure of Adduct of a New Schiff Base Macrocycle with Two THF: THIONE_2B_4[36]ENE-O_6N_8·2THF[J].Chinese Chemical Letters,1996,7(10):884-885.
3董世明,王夺元.Photophysical Properties of the Asymmetric Pentaazadentate Porphyrin-like Macrocycles[J].Science China Chemistry,1994,37(4):402-409.
4Yang, B,Yun, LH.THE SYNTHESIS OF NEW BENZODIAZEPINIC TRICYCLIC COMPOUNDS[J].Chinese Chemical Letters,1995,6(11):939-940.
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Chinese Chemical Letters

1993年第3期

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THE LINEAR CORRELATIONS BETWEEN ELECTRONIC TRANSITION ENERGY AND HAMMETT CONSTANTS FOR THE SUBSTITUTED PORPHYRIN-LIKE MACROCYCLE

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