摘要
Reaction of tetrakis(p-allyloxyphenyl)porphyrin and perfluoroalkanesulfonyl bromides gives tetrakis(p-polyfluoroalkoxylphenyl)substituted porphyrins.The yields are over 90%.The synthesis of the metal ion complexes of these F-containing porphyrins is also reported.Preliminary results on the study of the catalytic activity of the manganese(Ⅲ)complexes of various fluorinated porphyrins on oxidation of cyclohexene indicate that the introduction of R_F group into porphyrin contributes to the stability of the catalysts.
Reaction of tetrakis(p-allyloxyphenyl)porphyrin and perfluoroalkanesulfonyl bromides gives tetrakis(p-polyfluoroalkoxylphenyl)substituted porphyrins.The yields are over 90%.The synthesis of the metal ion complexes of these F-containing porphyrins is also reported.Preliminary results on the study of the catalytic activity of the manganese(Ⅲ)complexes of various fluorinated porphyrins on oxidation of cyclohexene indicate that the introduction of R_F group into porphyrin contributes to the stability of the catalysts.
