摘要
The syntheses of three cobalt(Ⅱ) complexes of tridentate Schiff bases and their dioxygen affinities in different solvents are reported. The complexes are N-salicylidene-L-alanine dihydrated cobalt(Ⅱ) (CoSAAL (H2O)2), N-salicylidene-L-leucine monohydrated cobalt (Ⅱ) (CoSALL(H2O)) and N-salicylidene-L-phenylalanine dihydrated cobalt(Ⅱ) (CoSALPHENA(H2O)2). The solents employed are pyridine (Py) anddimethylformamide (DMF).
The syntheses of three cobalt(Ⅱ) complexes of tridentate Schiff bases and their dioxygen affinities in different solvents are reported. The complexes are N-salicylidene-L-alanine dihydrated cobalt(Ⅱ) (CoSAAL (H2O)2), N-salicylidene-L-leucine monohydrated cobalt (Ⅱ) (CoSALL(H2O)) and N-salicylidene-L-phenylalanine dihydrated cobalt(Ⅱ) (CoSALPHENA(H2O)2). The solents employed are pyridine (Py) anddimethylformamide (DMF).
