摘要
The method of synthesizing ternary solid mixed ligand complexes from 1,10-phenanthroline, 2,2’-bipyridyl is reported. The series of complexes have been characterized by elemental analysis, infrared spectra, DSC-TGA analyses and molar conductivity. The results agree with the general formula LnL<sub>1</sub>L<sub>2</sub>Cl<sub>3</sub>·nH<sub>2</sub>O (Ln=La,Pr,Nd,Sm, Eu; Gd, Dy, Er, Tm, L<sub>1</sub>=phen, L<sub>2</sub>=bipy, n= 1,2,3).
The method of synthesizing ternary solid mixed ligand complexes from 1,10-phenanthroline, 2,2'-bipyridyl is reported. The series of complexes have been characterized by elemental analysis, infrared spectra, D3C-TGA analyses and molar conductivity. The results agree with the general formula LnL_1L2Cl3 · nH2O (Ln= La,Pr,Nd,Sm, Eu; Gd, Dy, Er, Tm, L_1 = phen, L2=bipy, n= 1,2,3).