摘要
In the media of 0.66,0.96, 2. 16 and 0.54 mol/L ofH2SO4,the heteropoly acids of As,P.Si and Ge are separately reduced to corresponding heteropoly blues by gibberellin, which exhibit maxirnum absorptions at 835, 820, 810 and 805 nm with molar absorptivities of 2.64x104, 2.54x104 3.51x104 and 2.25x104 L.mol-1'cm-1 and linear ranges of 0-30,0-15,0-10 and 0-30 μg/25mL, The method was applied to the determinations of As, P and Si in alloyed steel.
In the media of 0.66,0.96, 2. 16 and 0.54 mol/L ofH2SO4,the heteropoly acids of As,P.Si and Ge are separately reduced to corresponding heteropoly blues by gibberellin, which exhibit maxirnum absorptions at 835, 820, 810 and 805 nm with molar absorptivities of 2.64x104, 2.54x104 3.51x104 and 2.25x104 L.mol-1'cm-1 and linear ranges of 0-30,0-15,0-10 and 0-30 μg/25mL, The method was applied to the determinations of As, P and Si in alloyed steel.
