摘要
A novel pentaazadentate bismacrocycle was synthesized through an improved procedure of 1:1 Schiff base condensation of diformyltripyrrane with 3, 4, 3', 4'-tetraamino-biphenyl hydrochloride using Pb2+ as template ion, in which the condensed byproduct water was removed efficiently to make the yield over 90%. Then the bismacrocyclic ligand reacted with cadmium chloride to Field the title metal complex with molecular weight being 1200.4 by TOF MS and the lambda(max) being 766 nm.
A novel pentaazadentate bismacrocycle was synthesized through an improved procedure of 1:1 Schiff base condensation of diformyltripyrrane with 3, 4, 3', 4'-tetraamino-biphenyl hydrochloride using Pb2+ as template ion, in which the condensed byproduct water was removed efficiently to make the yield over 90%. Then the bismacrocyclic ligand reacted with cadmium chloride to Field the title metal complex with molecular weight being 1200.4 by TOF MS and the lambda(max) being 766 nm.
基金
Project (No. 29832030, 2982001) supported by the National Natural Science Foundation of China.
