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Synthesis,characterization and application of soluble fullerenated polymer materials

Synthesis,characterization and application of soluble fullerenated polymer materials
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摘要 This article only deals with the topic of intense interest to us and to a considerable extent of our own experimental results on the synthesis, characterization and application of C60-containing functional polymers such as poly(N-vinylcarbazole), polystyrene and polyacrylonitrile-based fullerene polymers. The results demonstrate that [60]fullerene and be directly incorporated into a variety of functional polymers by copolymerization or grafting, but also can be used to modify or improve the electronic, optical and physicochemical properties of polymers. Both the stereo-electroniceffect and me steric hindrance of C60 have an important influence on the structure and physicochemical properties of the parent polymer. This article only deals with the topic of intense interest to us and to a considerable extent of our own experimental results on the synthesis, characterization and application of C60-containing functional polymers such as poly(N-vinylcarbazole), polystyrene and polyacrylonitrile-based fullerene polymers. The results demonstrate that [60]fullerene and be directly incorporated into a variety of functional polymers by copolymerization or grafting, but also can be used to modify or improve the electronic, optical and physicochemical properties of polymers. Both the stereo-electroniceffect and me steric hindrance of C60 have an important influence on the structure and physicochemical properties of the parent polymer.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2000年第5期651-663,共13页 中国化学(英文版)
基金 Project supported by the National Natural Science Foundation of China (No. 29671007, 29890216)
关键词 FULLERENE functional polymers PREPARATION APPLICATION Fullerene functional polymers preparation application
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参考文献72

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