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Contrasting on Hydrocarbon Generation Modeland Characteristics of Pyrolysis of Modern Aquatic Plant(Gloeocapsa) vs MarineAnimal(Mantis Shrimp)

Contrasting on Hydrocarbon Generation Model and Characteristics of Pyrolysis of Modern Aquatic Plant (Gloeocapsa) vs Marine Animal (Mantis Shrimp)
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摘要 A hydrocarbon model of the modern aquatic plant Gloeocapsa and the aquatic animal mantis shrimp was found in thermal simulating experiment. The results show that the modern aquatic plant Gloeocapsa is characterized by late generation, late termination and a long duration of oil generation, while the aquatic animal mantis shrimp is characterized by early generation, early termination and a short duration of oil generation. The nalkanes from Gloeocapsa and mantis shrimp are characterized by peak carbon C 15 -C 17 . With increasing thermal simulating temperature, the peak carbon changes from C 17 to C 15 , and the odd-even predominance of nalkanes becomes less clear. The products from Gloeocapsa contain abundant phenanthrene and naphthalene compounds, and even a little retene, while those from mantis shrimp are dominated by naphthalene compounds, and are poor in phenanthrene compounds. Gloeocapsa and mantis shrimp are rich in C 27 sterane, relatively rich in tricyclic terpanes (C 19 -C 29 ) and hopanes (C 27 -C 35 ), poor in 5α,14β,17β sterane, and coprostane does not disappear until 450 ℃. The tricyclic terpanes in Gloeocapsa are characterized by peak carbon C 23 and C 23 >C 21 , and in mantis shrimp by C 21 and C 21 >C 23 . The content of pregnanes is very low at low temperature of thermal simulation, while above 360 ℃, high levels of pregnane series compounds and even degraded C 25 and C 26 steranes occur in thermal simulation products. A hydrocarbon model of the modern aquatic plant Gloeocapsa and the aquatic animal mantis shrimp was found in thermal simulating experiment. The results show that the modern aquatic plant Gloeocapsa is characterized by late generation, late termination and a long duration of oil generation, while the aquatic animal mantis shrimp is characterized by early generation, early termination and a short duration of oil generation. The nalkanes from Gloeocapsa and mantis shrimp are characterized by peak carbon C 15 -C 17 . With increasing thermal simulating temperature, the peak carbon changes from C 17 to C 15 , and the odd-even predominance of nalkanes becomes less clear. The products from Gloeocapsa contain abundant phenanthrene and naphthalene compounds, and even a little retene, while those from mantis shrimp are dominated by naphthalene compounds, and are poor in phenanthrene compounds. Gloeocapsa and mantis shrimp are rich in C 27 sterane, relatively rich in tricyclic terpanes (C 19 -C 29 ) and hopanes (C 27 -C 35 ), poor in 5α,14β,17β sterane, and coprostane does not disappear until 450 ℃. The tricyclic terpanes in Gloeocapsa are characterized by peak carbon C 23 and C 23 >C 21 , and in mantis shrimp by C 21 and C 21 >C 23 . The content of pregnanes is very low at low temperature of thermal simulation, while above 360 ℃, high levels of pregnane series compounds and even degraded C 25 and C 26 steranes occur in thermal simulation products.
出处 《Journal of Earth Science》 SCIE CAS CSCD 2000年第1期30-38,共9页 地球科学学刊(英文版)
基金 the project 211at China University of Geosciences
关键词 Gloeocapsa mantis shrimp hydrocarbon generation thermal simulation molecular geochemistry. Gloeocapsa, mantis shrimp, hydrocarbon generation, thermal simulation, molecular geochemistry.
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