摘要
Several series of LiRE x Mn 2-x O 4(RE=Ce, Nd) samples prepared at different contents and in different rare earth metals substitution were studied in order to further understand the dependence of the electrochemical performance on the doping rare earth metals. These cathodes were more tolerant to repeat lithium extraction and insertion than a standard LiMn 2O 4 spinel electrode in spite of a small reduction in the initial capacity. X ray photoelectron spectroscopy results show that the Mn 4+ contents for spinel LiMn 2O 4 directly affected the initial capacity and cyclability of LiMn 2O 4.
Several series of LiRE x Mn 2-x O 4(RE=Ce, Nd) samples prepared at different contents and in different rare earth metals substitution were studied in order to further understand the dependence of the electrochemical performance on the doping rare earth metals. These cathodes were more tolerant to repeat lithium extraction and insertion than a standard LiMn 2O 4 spinel electrode in spite of a small reduction in the initial capacity. X ray photoelectron spectroscopy results show that the Mn 4+ contents for spinel LiMn 2O 4 directly affected the initial capacity and cyclability of LiMn 2O 4.
