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Synthesis and characterization of Cu-Pt/MWCNTs for use in electrocatalytic applications 被引量:3

Synthesis and characterization of Cu–Pt/MWCNTs for use in electrocatalytic applications
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摘要 Improving catalyst performance by studying the preparation parameters, material structures and analysis methods is important work for catalyst researchers. In this study, Cu-Pt nanocomposites with different metal ratios were synthesized on MWCNTs using a polyol method. The structures and morphologies of the nano hybrid catalysts were analyzed by XRD and TEM. The XRD results indicate that Pt and Cu formed a bimetallic solid solution. The average diameters of the Pt and Cu-Pt nanoparticles on MWCNTs were between 3-10 nm and 5-15 nm, respectively. The electrocatalytic behavior of methanol oxidation reactions was investigated by cyclic voltammery (CV). Cu(20%)/[Pt/MWCNTs(1:4)], which contained an optimal degree of solid solution, enhanced the methanol oxidation to the greatest degree. Improving catalyst performance by studying the preparation parameters, material structures and analysis methods is important work for catalyst researchers. In this study, Cu-Pt nanocomposites with different metal ratios were synthesized on MWCNTs using a polyol method. The structures and morphologies of the nano hybrid catalysts were analyzed by XRD and TEM. The XRD results indicate that Pt and Cu formed a bimetallic solid solution. The average diameters of the Pt and Cu-Pt nanoparticles on MWCNTs were between 3-10 nm and 5-15 nm, respectively. The electrocatalytic behavior of methanol oxidation reactions was investigated by cyclic voltammery (CV). Cu(20%)/[Pt/MWCNTs(1:4)], which contained an optimal degree of solid solution, enhanced the methanol oxidation to the greatest degree.
出处 《Particuology》 SCIE EI CAS CSCD 2011年第5期522-527,共6页 颗粒学报(英文版)
基金 the financial support of the Taiwan National Science Council
关键词 Electrocatalysis Methanol Multi-walled carbon nanotubes NanoparticlesPlatinumCopper Electrocatalysis Methanol Multi-walled carbon nanotubes NanoparticlesPlatinumCopper
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