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树枝酞菁锌-单壁碳纳米管复合体系的合成 被引量：2

Synthesis of Functionalized Single-walled Carbon Nanotubes with Dendritic Phthalocyanines
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摘要 利用乙二胺对单壁碳纳米管进行氨基化修饰,进一步与四-[3,5-(二-4-羧基苯甲氧基)-苯甲氧基]锌酞菁发生酰基化反应.树枝酞菁锌-单壁碳纳米管化合物相对纯单壁碳纳米管能更好的溶解于有机溶剂二甲基甲酰胺中.通过紫外-可见吸收光谱和热重分析对所合成的树枝酞菁锌-单壁碳纳米管化合物进行了表征.本研究为碳纳米管在生物医学中的应用提供实验理论依据. The motivation of this study was the fabrication of nanotube-based zine-phthalocyanine（ZnPc） ,which may be a promising functional material. In this article,the functionalization of single-walled carbon nanotubes （SWNTs） was described with ethylenediamine and the subsequent attachment of the ZnPc derivative, tetra- （ 3,5-di （4-carboxyl benzyloxy）-benzyloxy） zinc phthalocyanine, u- sing the reliable acylation reaction. The resulting SWNTs-ZnPc conjugate exhibits more excellent solubility in dimethyl formamide （DMF） than SWNTs, and was characterized by ultravioiet-visible spectrophotometry （UV-vis） and thermogravimetric analysis （TGA）.
作者 吴克勤 刘静 马冬冬 贺丹丹 陈婉玲 林秋云 邱燕珠 彭亦如
机构地区 福建师范大学化学与材料学院
出处 《厦门大学学报（自然科学版）》 CAS CSCD 北大核心 2011年第B09期70-73,共4页 Journal of Xiamen University：Natural Science
基金 国家自然科学基金项目(20604007) 福建省科技厅重点项目(2007J0013) 福建省自然科学基金项目(2008J0078) 卫生部科学研究基金项目(WKJ2008-2-61) 福建省大学生创新性实验计划项目(BKL2010-027)
关键词 树枝酞菁 单壁碳纳米管 紫外-可见吸收光谱 热重分析 dendritic phtbalocyanines single-walled carbon nanotubes ultraviolet-visible absorption spectroscopy thermogravimetric analysis
分类号 Q356.1 [生物学—遗传学]
  • 相关文献

参考文献13

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共引文献5

同被引文献28

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厦门大学学报（自然科学版）
2011年 第B09期

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