摘要
用乳液聚合的方法由丙烯请（AN）、苯乙烯（St）和α-甲基苯乙烯（α－MSt）合成了三元共聚物（PASMS），用扭辫分析仪（TBA）和扫描电子显微镜（SEM）研究了共聚物与氯化聚乙烯（CPE）的相容性，结果说明，含有α－MSt的共聚物与CPE有较好的相容性，并且有良好的流变行为。熔体的表现粘度随剪切速率的增加而下降，呈现假塑性流变行为。
The copolymer PASMS was synthesized from acrylonitrile(AN),styrene(St)and α-methylstyrene(α-M St)by emulsion polymerization.The compatibility of PASMS with chlorinated polyethylene(CPE)was estimated by the methods of torsional braid analysis(TBA) and scanning electron microscopy(SEM)after mechanical blending.The results show that the α-M St has a compatibilization effect on the blend ACS of the CPE with the copolymer PAS formed from AN and St. The α-methylstyrene containing ACS resin has a better rheogical behavior. The apparent viscosity in the melt decreases with the increasing shear rate,and the melt has the behavior of pseudoplastic liquid.
出处
《河北大学学报（自然科学版）》
CAS
1999年第4期343-346,共4页
Journal of Hebei University(Natural Science Edition)
基金
河北省自然科学基金!596068
