摘要
氧可与有机分子形成接触电荷转移（ＣＣＴ）复合物。本文阐述了Ｏ２－ＣＣＴ 复合物的形成机制、部位与平衡及其紫外吸收特点，综术了Ｏ２－ＣＣＴ 复合物在有机物氧化、电离势测定、氧传感器、烃类选择氧化及光聚合等领域的研究与应用进展。
Oxygen as an electron acceptor can interact with organic electron donors to form oxygen contract charge transfer (O 2 CCT) complexes.The formation mechanism,the formation site and equilibrium of O 2 CCT complexes as well as their absorptin characteristics are expounded.The research and application of O 2 CCT complexes in oxidation of organic compounds,determination of ionization potential,oxygen sensor,and photopholymerization are lso reviewed.
出处
《化学通报》
CAS
CSCD
北大核心
1999年第9期14-20,共7页
Chemistry
基金
国家自然科学基金
关键词
电荷转移复合物
氧-接触
电荷转移
O2-CCT
Charge Transfer (CT) complex, Oxygen Contact Charge Transfer (O 2 CCT) complex,absorption spectra,oxidation
