摘要
以NazSiO3·9H2O为原料，浓H2sO4为酸试剂，采用化学沉淀法制备纳米二氧化硅，讨论Na2SiO3浓度、搅拌速度、pH值、分散剂Na2S04和表面活性剂聚乙二醇等因素对产物特性的影响，并用红外光谱、透射电镜、扫描电镜和X射线衍射等分析手段对二氧化硅纳米颗粒进行结构和形貌表征。利用本体聚合法制备了聚甲基丙烯酸甲酯一纳米二氧化硅复合材料，研究纳米二氧化硅颗粒对聚甲基丙烯酸甲酯材料力学性能的增强作用以及透光度的影响。结果表明：二氧化硅纳米粒子呈球形，粒径在50～100nm范围内、分布均匀、呈无定形；填充纳米二氧化硅的复合材料的冲击强度和弯曲强度明显提高。
Silica nano-particles were prepared via chemical precipitation using Na2SiO3.9H20 and H2SO4. The effects of several technical factors on the properties of silica powders, such as Na2SiO3 concentrations, pH, agitation speed, dispersant Na2SO4 and surfactant PEG were studied. FT-IR, TEM, SEM and XRD were used to characterize the structure and morphology of the silica powders. The polymethylmethacrylate （PMMA） -silica nano-composites were prepared by in-situ bulk polymerization after silica nano-particles mixing with methylmethacrylate （MMA） monomer through ball milling. Finally, the reinforcing effect and the transparence of PMMA slices of silica nano-particles on PMMA were also investigated. The results showed that the as-prepared SiO2 particles were amorphous, spherical with uniform size distribution and the particles size could be controlled in the range from 50 to 100 nm. The impact strength and flexural strength of the composite materials filled SiO2 nano-particles was improved obviously.
出处
《中国粉体技术》
CAS
北大核心
2011年第3期63-67,共5页
China Powder Science and Technology
基金
国家自然科学基金项目
编号:20876100
20736004
国家重点基础研究发展计划(973计划)项目
编号:2009CB219904
国家博士后科学基金项目
编号:20090451176
科技部创新基金项目
江苏省博士后科学基金项目
苏州科技局项目
编号:YJS0917
SG0978
苏州高新区领军人才计划
福建省闽江学者奖励计划
