摘要
The title compound,a mixed（phthalocyaninato）（porphyrinato） yttrium double-decker complex 1,has been synthesized and structurally characterized by X-ray single-crystal diffraction method.Crystal data：monoclinic,space group C2/c,Z = 8,C79H52Cl10N12O4Y,Mr = 1676.74,a = 38.217（3）,b = 18.9867（13）,c = 26.200（3） ,β = 128.0190（10）°,V = 14977（2） 3,Dc = 1.487 g/cm3,μ（MoKα） = 1.196 mm-1,F（000） = 6808,R = 0.0745 and wR = 0.2208 for observed reflections with I 〉2σ（I）.X-ray analysis reveals that the coordination polyhedron adopts a slightly distorted square-antiprismatic structure around the metal center.Both phthalocyanine and porphyrin ligands are saucer-shaped,with the skew angle of the two ligand planes approximately 45°.
The title compound,a mixed（phthalocyaninato）（porphyrinato） yttrium double-decker complex 1,has been synthesized and structurally characterized by X-ray single-crystal diffraction method.Crystal data：monoclinic,space group C2/c,Z = 8,C79H52Cl10N12O4Y,Mr = 1676.74,a = 38.217（3）,b = 18.9867（13）,c = 26.200（3） ,β = 128.0190（10）°,V = 14977（2） 3,Dc = 1.487 g/cm3,μ（MoKα） = 1.196 mm-1,F（000） = 6808,R = 0.0745 and wR = 0.2208 for observed reflections with I 〉2σ（I）.X-ray analysis reveals that the coordination polyhedron adopts a slightly distorted square-antiprismatic structure around the metal center.Both phthalocyanine and porphyrin ligands are saucer-shaped,with the skew angle of the two ligand planes approximately 45°.
基金
Supported by the National Natural Science Foundation of China (No. 20801031)
the Natural Science Foundation of Shandong Province (No. Q2008B01)
the Doctoral Foundation of Shandong Province (No. 2007BS02016)
Independent Innovation Foundation of SDU
