摘要
综述了高压下溶液中化学反应的活化体积△V~≠的定义和测定方法,以及作为配合物取代反应、异构化反应、电子转移反应和光化学反应机理的判据。
Under high pressure definition and measurement of volume of activation for chemical reactions in solutions are reviewed. The volumes of activation may be used to diagnose the mechanisms of substitution reactions and isomerization reactions and electron transfer reactions and photochemical reactions of coordination compounds.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1990年第4期477-481,共5页
Chinese Journal of Inorganic Chemistry
关键词
配合物
反应动力学
高压
活化体积
high pressure volume of activation kinetics of complex reaction
