Magnetocaloric effect and magnetic properties of La_(0.9)Ce_(0.1)(Fe_(0.99)Mn_(0.01))_(11.6)Si_(1.4)H_(1.6) compound

Magnetocaloric effect and magnetic properties of La_(0.9)Ce_(0.1)(Fe_(0.99)Mn_(0.01))_(11.6)Si_(1.4)H_(1.6) compound

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摘要 Magnetocaloric effect and magnetic properties of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4 and its hydride La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 were investigated. The Curie temperature of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4 was increased by hydrogen absorption. XRD patterns showed that the structure of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 remained NaZn13-type. The Curie temperature （TC） of the sample was increased from 174 K to 331 K. The homogeneity of the hydrogen absorption for La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 was proven very well by the random measurement of DSC. The magnetic entropy △SM of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 had peak at 326 K. The peak value of-△SM-was 12.3 and 7.8 J/（kg.K） under magnetic field change of 0–2 T and 0–1 T,respectively,which was comparable with Gd5Si2Ge2. The negative slope and inflection point of the Arrott curve indicated that the first-order magnetic transition of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4 was reserved after hydrogen absorption. Magnetocaloric effect and magnetic properties of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4 and its hydride La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 were investigated. The Curie temperature of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4 was increased by hydrogen absorption. XRD patterns showed that the structure of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 remained NaZn13-type. The Curie temperature （TC） of the sample was increased from 174 K to 331 K. The homogeneity of the hydrogen absorption for La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 was proven very well by the random measurement of DSC. The magnetic entropy △SM of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4H1.6 had peak at 326 K. The peak value of-△SM-was 12.3 and 7.8 J/（kg.K） under magnetic field change of 0–2 T and 0–1 T,respectively,which was comparable with Gd5Si2Ge2. The negative slope and inflection point of the Arrott curve indicated that the first-order magnetic transition of La0.9Ce0.1（Fe0.99Mn0.01）11.6Si1.4 was reserved after hydrogen absorption.

作者王超伦龙毅马涛张虎

机构地区 School of Materials Science and Engineering

出处《Journal of Rare Earths》 SCIE EI CAS CSCD 2011年第5期474-476,共3页 稀土学报（英文版）

基金 Project supported by the National Basic Research Program of China (2006CB601101) the National High Technology Research and Development Program of China (2007AA03Z440) the National Natural Science Foundation of China (50731007)

关键词 homogeneity of hydrogen absorption magnetocaloric effect magnetic entropy change rare earths homogeneity of hydrogen absorption magnetocaloric effect magnetic entropy change rare earths

分类号 TM271 [一般工业技术—材料科学与工程]

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参考文献2

1Karl A Gschneidner,Vitalij K Pecharsky.Rare Earths and Magnetic Refrigeration[J].Journal of Rare Earths,2006,24(6):641-647. 被引量：20
2王芳,陈远富,王光军,孙继荣,沈保根.Large magnetic entropy change and magnetic properties in La （Fel－xMnx）ll.TSil.3Hy compounds[J].Chinese Physics B,2003,12(8):911-914. 被引量：3

二级参考文献31

1Shen Y T, Guo Z B and Du Y W 1999 Acta Phvs, Sin.48 2137 (in Chinese). 被引量：1
2Wang D H, Yin J H, Tang S L, Sheng Y T and Du Y W 1999 Acta Phys. Sin. 48 S116 (in Chinese). 被引量：1
3Chen P, Wang D H, Tang S L: Shen Y T and Du Y W 1999 Acta Phys. Sin. 48 S121 (in Chinese). 被引量：1
4Chen W, Zhong W, Pan C F,Chang H and Du Y W 2001 Acta Phys. Sin. 50 319 (in Chinese). 被引量：1
5Tegus Oi Brück E, Buschow K H J and de Boer F R 2002 Nature 415 150. 被引量：1
6Hu F X, Shen B G, Sun J R and Zhang X X 2000 Chin.Phys. 9 550. 被引量：1
7Hu F X, Shen B G, Sun J R, Cheng Z H, Rao G H and Zhang X X 2001 Appl. Phys. Lett. 78 3675. 被引量：1
8Hu F X, Shen B G, Sun J R, Pakhomov A B, Wong C Y,Zhang X X, Zhang S Y, Wang G J and Cheng Z H 2001 IEEE. Trans. Magnetics 37 2328. 被引量：1
9Hu F X, Shen B G, Sun J R and Cheng Z H 2001 Phys.Rev. B 64 132412. 被引量：1
10Hu F X, Wang G J, Sun J R, Zhang X X, Cheng Z H and Shen B G 2002 J. Appl. Phys. 91 7836. 被引量：1

共引文献21

1邓健秋,祝金明,严嘉琳,庄应烘,王日初.Magnetocaloric Effect of Alloys Gd(Al_(1-x)Co_x)_2[J].Journal of Rare Earths,2007,25(6):783-786. 被引量：1
2张虎,鲍博,史普辑,傅斌,龙毅,常永勤,万发荣.Phase formation with NaZn_(13) structure in metamagnetic La(Fe_(1–x)Co_x)_(11.9)Si_(1.1) compounds[J].Journal of Rare Earths,2008,26(5):727-730. 被引量：1
3丁雅韵,张智勇,周鹏举,刘金昌,王志民,赵宇亮.Research and Development of Gadolinium Loaded Liquid Scintillator for Daya Bay Neutrino Experiment[J].Journal of Rare Earths,2007,25(S1):310-313. 被引量：1
4韩志达,钱斌,张平,江学范,王敦辉,陈杰,冯金福,都有为.Low-field magnetic entropy changes in (Gd_(1-x)Y_x)_3Al_2 alloys[J].Journal of Rare Earths,2011,29(3):235-238.
5韩志达,陈杰.Dy(Co_(1-x)Mn_x)_2合金的相变和磁热效应[J].常熟理工学院学报,2011,25(4):23-26. 被引量：1
6韩志达,郑志华.高锰含量Mn_(50+x)Ni_(41-x)Sn_9合金的相变和磁热效应[J].常熟理工学院学报,2012,26(2):36-40.
7史倩仪,许淑娟,居晶华,韩志达,钱斌,江学范.(Dy_(1-x)Y_x)Co_2合金的低场巨磁热效应[J].常熟理工学院学报,2015,29(2):59-62. 被引量：2
8曲瑞,江奕东,徐霸津,丁晶晶,廖成,凌国平.Anodic behavior of neodymium in acidic AlCl_3-1-ethyl-3-methyl-imidazolium chloride ionic liquid[J].Journal of Rare Earths,2015,33(7):776-782. 被引量：1
9Sudharshan Vadnala,Prem Pal,Saket Asthana.Influence of A-site cation disorder on structural and magnetocaloric properties of Nd_(0.7–x)La_xSr_(0.3)MnO_3(x=0.0, 0.1, 0.2 & 0.3)[J].Journal of Rare Earths,2015,33(10):1072-1080. 被引量：3
10曲瑞,凌国平.钕在[BMP]Tf_2N离子液体中的阳极行为[J].材料科学与工程学报,2016,34(1):12-17. 被引量：3

1WU Wei Feng Zai Guo Lijun.Magnetic Entropy Change of (Gd_(1-x)RE_x)_5Si_4(RE=Dy, Ho) Alloys[J].Journal of Rare Earths,2005,23(4):441-441.
2DENG Jianqiu,CHEN Xiang,ZHUANG Yinghong.Effect of gallium doping on the magnetocaloric effect of LaFe_(11.2)Co_(0.7)Si_(1.1)[J].Rare Metals,2008,27(4):345-349. 被引量：2
3马建波,湛永钟,周卫平,黄国瑞,刘佑良,林栽汉.磁热效应和室温稀土磁制冷材料研究现状[J].材料导报,2008,22(11):34-37. 被引量：9
4W. Cheikhrouhou-Koubaa,A. Cheikhrouhou.Magnetocaloric Effect Near Room Temperature in Composites Based on Lal.xCax.yAyMnO3 Manganites （A=K, Na）[J].Journal of Physical Science and Application,2016,6(1):2-2.
5张虎,鲍博,史普辑,傅斌,龙毅,常永勤,万发荣.Phase formation with NaZn_(13) structure in metamagnetic La(Fe_(1–x)Co_x)_(11.9)Si_(1.1) compounds[J].Journal of Rare Earths,2008,26(5):727-730. 被引量：1
6G.F. Wang,L. Song,Z.Q. Ou,Z.R. Zhao,O. Tegus.CALCULATION OF THE MAGNETIZATION AND MAGNETOCALORIC EFFECT IN THE MnFeP_(0.45)As_(0.55) COMPOUND[J].Acta Metallurgica Sinica(English Letters),2007,20(4):265-269. 被引量：1
7E.Yüzüak,I.Dincer,Y.Elerman.Magnetocaloric properties of the Gd_5Si_(2.05-x)Ge_(1.95-x)Mn_(2x) compounds[J].Journal of Rare Earths,2010,28(3):477-480. 被引量：2
8邹君鼎,沈保根,孙继荣.Magnetic properties and magnetocaloric effect in TbCo2-xFex compounds[J].Chinese Physics B,2007,16(12):3843-3847.
9O. Tegus,Yirgeltu.Magnetocaloric Effect in MnCo_(1-x)Al_xGe Compounds[J].Journal of Materials Science & Technology,2009,25(6):781-784. 被引量：3
10吴小峰,黄科科,侯长民,葛磊,初学峰,王珊,冯守华.脉冲激光沉积制备La_(0.62)Ca_(0.29)K_(0.09)MnO_3外延膜及其磁热性能[J].高等学校化学学报,2013,34(9):2063-2067.

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Magnetocaloric effect and magnetic properties of La_(0.9)Ce_(0.1)(Fe_(0.99)Mn_(0.01))_(11.6)Si_(1.4)H_(1.6) compound

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