摘要
燃煤过程中NOx 的排放是一个复杂的过程, 既包括NOx 的生成过程又包括生成的NOx 进行均相和多相还原反应. 简述了煤燃烧过程中NOx 生成和还原的机理. 认为燃料氮是NOx的主要来源,NOx 的排放与煤阶、煤中氮含量以及温度等因素有关;NOx 与半焦的多相反应是NOx还原的主要原因, 其中包括NOx 在半焦表面的化学吸附。
The emission of NO x during coal combustion is a very complex process, inclu ding the formation of NO x and the formed NO x undergoes homogeneous gas phase reduction and heterogeneous gas solid reduction. This paper reviewed the formation and reduction mechenisms of NO x . Fuel N is the main source of NO x . The emission of NO x depends on many factors, such as the rank of coal, the content of nitrogen, the structure of char and combustion temperature. The NO x char heterogeneous reaction is the most significant reaction of NO x reduction which includes chemisorption of NO x on the char surface, the formation of surface complexes and the release of products.\;
出处
《煤炭转化》
CAS
CSCD
1999年第4期10-15,共6页
Coal Conversion