摘要
The tea wastages could remove methylene blue(MB) as a cationic dye from waste water corresponding to second-order kinetic model.Thermodynamic studies showed that adsorption equilibrium constant(KL) and maximum adsorption capacities(Q(max)) were increased with increasing temperature.The removal efficiency of MB for Co 0.01 mmol/L at optimum conditions was about 85%. The maximum uptake capacity(Q(max)) of methylene blue in a batch reactor was 0.328,0.542 and 0.659 mmol/g at 15,25 and 40℃, respectively.The enthalpy change(ΔH) and entropy change(ΔS) were 11.356 kJ/mol and 20.563 J/(mol K),respectively.
The tea wastages could remove methylene blue(MB) as a cationic dye from waste water corresponding to second-order kinetic model.Thermodynamic studies showed that adsorption equilibrium constant(KL) and maximum adsorption capacities(Q(max)) were increased with increasing temperature.The removal efficiency of MB for Co 0.01 mmol/L at optimum conditions was about 85%. The maximum uptake capacity(Q(max)) of methylene blue in a batch reactor was 0.328,0.542 and 0.659 mmol/g at 15,25 and 40℃, respectively.The enthalpy change(ΔH) and entropy change(ΔS) were 11.356 kJ/mol and 20.563 J/(mol K),respectively.
基金
the Islamic Azad University,Lahijan and Rasht Branches for their help and support