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Oxidative Coupling of Methane over Li/MgO: Catalyst and Nanocatalyst Performance 被引量:1

甲烷氧化偶联锂/氧化镁催化剂和纳米催化剂
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摘要 The Li/MgO catalyst and nanocatalyst were prepared by the incipient wetness impregnation and sol-gel method, respectively. The catalytic performance of the Li/MgO catalyst and nanocatalyst on oxidative coupling of methane was compared. The catalysts prepared in two ways were characterized by X-ray powder diffraction, Brunauer-Emmett-Teller surface and transmission electron microscope. The catalyst was tested at temperature of 973-1073 K with constant total pressure of 101 kPa. Experimental results showed that Li/MgO nanocatalyst in the oxidative coupling of methane would result in higher conversion of methane, higher selectivity, and higher yield of main products (ethane and ethylene) compared to ordinary catalyst. The results show the improved influence of nanoscale Li/MgO catalyst performance on oxidative coupling of methane.
出处 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2011年第1期70-76,I0004,共8页 化学物理学报(英文)
关键词 Oxidative coupling of methane NANOCATALYST SOL-GEL 甲烷氧化偶联 纳米催化剂 溶胶凝胶法
分类号 O [理学]
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