摘要
8种不同的二茂铁甲醇衍生物与BF3?Et2O在二氯甲烷中作用形成相应的碳正离子,不需从溶液中提纯,即可与硫代乙酸钾反应得到取代产物α-二茂铁基硫代乙酸酯,并通过元素分析、红外光谱、核磁共振氢谱对其结构进行了表征.
Eight different ferrocenylmethanol derivatives were treated with BF3oEt2O in CH2Cl2 to generate the corresponding carbocations.The carbocations consequently reacted with potassium thioacetate without isolation to afford α-ferrocenylthioacetate.All the final products were characterized by elemental analysis,IR,and 1H NMR spectra.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2011年第2期239-241,共3页
Chinese Journal of Organic Chemistry
基金
内蒙古自然科学基金(Nos.200308020103
2009BS0204)资助项目
