摘要
The reaction mechanism of decarbonylation of aliphatic acids to 1-alkenes by Pd(PPh3)2Cl2, which involues formation ofmixed anhydride, oxidation addition, insertion and antiinsertion, displacement of ligands, is suggested according to theexperimental finding and primary reaction of Pd(II) complexs catalyst.
The reaction mechanism of decarbonylation of aliphatic acids to 1-alkenes by Pd(PPh3)2Cl2, which involues formation ofmixed anhydride, oxidation addition, insertion and antiinsertion, displacement of ligands, is suggested according to theexperimental finding and primary reaction of Pd(II) complexs catalyst.
出处
《化学研究与应用》
CAS
CSCD
1999年第5期550-551,共2页
Chemical Research and Application
关键词
双三苯基膦
二氯化钯
脱羰
催化剂
端烯
bis(triphenylphosph in e)pallladium (II)chloride , decarbonylation, mechanism
