摘要
本文研究了固体Co(en)_3Cl_3和Cr(en)_3Cl_3(这里en代表乙二胺)在TEA CO_2激光作用下的红外多光子离解反应,其反应产物分别为光化学还原产物CoCl_2和二(乙二胺)配合物[Cr(en)_2Cl_2]Cl。作者认为 Co(en)_3Cl_3和 Cr(en)_3Cl_3的红外多光子离解反应是一激光热解过程。
The IR multiphoton decomposition reactions of the solid state Co(en3Cl3and Cr(cn)3Cl3by using TEA CO2laser have been investigated in this paper, their reaction products are photochemicaal reduction product CoC2and di(cthylencdiamine) complex [Cr(cn)2Cl2]Cl, respectively. The authors believe that the reaction of Co(cn)3Cl3or Cr(cm)3Cl3is a laser thermal decomposition process.
