摘要
由Bi2S3在NaCl溶液中的溶解度,Bi2S3-Cl-H2O系的电位-pH、电位-lg[Cl]图分析表明:Bi2S3矿在氯盐水溶液的溶解度有了很大的提高,在矿浆电解时它同时存在三种浸出机理,即1.化学溶解.2.化学氧化.3.阳极氧化溶液中Cu()与离子Fe()的存在有利于Bi2S3矿的浸出.
Analysis of solubility of Bi2S3 in natriUm chloride salt solution and E-pH, E-lg[Cl-] duagrans if Bi2S3-Cl-H2O system shows that the solubility of Bi2S3 in natrium chloride salt solution is improved obviouslyand three leaching mechanisms of Bi2S3 in electro-slurry process may occur simultaneously:1. Chemical dissolution : 2. Chemical oxidation: 3. Anodic oxidation: The existence of Fe3+ ion and Cu2+ ion in solution is beneficial to the leaching of Bi2S3
出处
《有色金属》
CSCD
1999年第3期56-59,共4页
Nonferrous Metals
关键词
矿浆电解
硫化铋矿
热力学
浸出
Bi2S3-Cl-H2O system
E-pH diagram
E-lg[Cl-] diagram
slurry electrolysis