摘要
0 Introduction Metal-organic polymeric frameworks have been rapidly expanding in recent years not only because of their potential applications in gas adsorption,ion exchange,
A novel cobalt（II） complex with biphenyl-3,3′,4,4′-tetracarboxylic acid（H4bptc） and 2-phenyl-1,3,7,8-tetraazacyclopenta[l]-phenanthrene（ptcp）,{[Co（H2bptc）（ptcp）（H2O）2]·H2O}n（1）,has been synthesized by hydro-thermal method and was characterized by elemental analysis,single crystal X-ray diffraction and thermal gravimetry（TG）.It crystallizes in monoclinic,space group Pn with a=0.719 44（14） nm,b=1.259 4（3） nm,c=1.681 9（3） nm,β=93.30（3）°,V=1.521 5（5） nm3,Z=2,C35H26CoN4O11,Mr=737.53,Dc=1.610 g·cm-3,μ（Mo Kα）=0.639 mm-1,F（000）=758,S=1.024,R1=0.076 7 and wR2=0.120 6.The structural analyses reveal that the title complex is a 1D zigzag chain strcture along the c axis,which is stacked to furnish a three-dimensional supramolecular net structure via hydrogen bonding interactions.CCDC： 793796.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2010年第12期2280-2284,共5页
Chinese Journal of Inorganic Chemistry
基金
江苏省博士后基金项目(No.0801010B)
江苏大学自然科学基金(No.09JDG001)资助
关键词
钴配合物
3
3′
4
4′-联苯四甲酸
超分子结构
cobalt complex
biphenyl-3
3′
4
4′-tetracarboxylic acid
supramolecular structure
