摘要
由非离子型表面活性剂、助表面活性剂(醇)、水和油形成微乳液,用拟三角相图中微乳区的面积确定形成微乳液的最佳条件.实验证明,油的碳原子数加上醇的碳原子数等于表面活性剂的碳原子数时为微乳液形成最佳条件。
The interrelation of carbon numbers was studied in microemulsions containing nonionic surfactant, n alcohol, n hydrocarbon and water by construction of pseduo ternary phase diagrams. Mixtures of the surfactant, alcohol and hydrocarbon were titrated at 30 ℃ with water to the points of turbidity and clarity to determine the microemulsion area. The total area of the microemulsion of different types for AEO 9, n alcohol, n hydrocarbon and water reached a maximum value when N O, carbon number of the oil, N O, carbon number plus that of the alcohol, N A, was equal to that of the AEO 9, N S( N S= N O+ N A). The results are discussed theoretically.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1999年第5期772-776,共5页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
微乳液
非离子型
表面活性剂
碳数相关性
相图
Microemulsion, Nonionic surfactant, Interrelation of carbon numbers, Phase diagram