摘要
In this study,the hydrogels composites with coatings based on a temperature-sensitive linear copolymer of N-tert-butylacrylamide(NTBA)and acrylamide(AAm)on cotton fabrics have been developed.The cotton fabrics were coated using aqueous solution of the linear copolymer,1,2,3,4-butanetertracarboxylic acid(BTCA)as a cross-linker and sodium hypophosphite(SHP)as a catalyst,followed by drying and curing.The effects of cross-linking reaction conditions in coating process on water-impermeable ability of coated cotton fabrics were investigated in detail.The results indicate that the coated fabrics have temperature sensitivity.The coatings of poly(NTBA-co-AAm)hydrogels were bonded on the surface of the cotton fabrics,as verified by SEM and optical microscopy,which gave the water-impermeable ability to the hydrogels composites.Moreover,the hydrogels formed in the coating process also identified that - COOH of BTCA reacted with -NH2 in the linear polymer and formed three-dimensional network hydrogels.FTIR and XPS were used to characterize the cross-linking reaction of - COOH of BTCA and - OH of cellulose.
In this study,the hydrogels composites with coatings based on a temperature-sensitive linear copolymer of N-tert-butylacrylamide（NTBA）and acrylamide（AAm）on cotton fabrics have been developed.The cotton fabrics were coated using aqueous solution of the linear copolymer,1,2,3,4-butanetertracarboxylic acid（BTCA）as a cross-linker and sodium hypophosphite（SHP）as a catalyst,followed by drying and curing.The effects of cross-linking reaction conditions in coating process on water-impermeable ability of coated cotton fabrics were investigated in detail.The results indicate that the coated fabrics have temperature sensitivity.The coatings of poly（NTBA-co-AAm）hydrogels were bonded on the surface of the cotton fabrics,as verified by SEM and optical microscopy,which gave the water-impermeable ability to the hydrogels composites.Moreover,the hydrogels formed in the coating process also identified that — COOH of BTCA reacted with —NH2 in the linear polymer and formed three-dimensional network hydrogels.FTIR and XPS were used to characterize the cross-linking reaction of — COOH of BTCA and — OH of cellulose.
基金
Research Fund for the Doctoral Programof Higher Education of China(No.20050058006)
