摘要
采用介质阻挡放电(DBD)低温N2、O2等离子体技术对黏胶基活性炭纤维(V-ACF)进行表面改性,运用BET、SEM、NH3-TPD和FT-IR对催化剂进行表征,并对催化剂低温选择性催化还原(SCR)NO性能进行了研究。结果表明,N2、O2等离子体最佳改性时间分别为5 min与10 min,最佳反应温度为100℃,低温等离子体改性能明显提高ACF上NO转化率,且N2等离子体改性ACF催化效率高于O2等离子体改性ACF。
Viscose-activated carbon fiber（V-ACF）modified by low-temperature N2 and O2 plasma with dielectric barrier discharge（DBD）was studied for low-temperature selective catalytic reduction（SCR） of NO.Structure of the plasma modified V-ACF was characterized by BET,SEM,NH3-TPD and FT-IR.Experimental results showed that the optimal surface modification time was 5 and 10 minutes for N2 and O2 plasma,respectively.The optimal reaction temperature was 100℃.Surface modification of V-ACF by low-temperature plasma technology could greatly improve the NO removal rate.V-ACF modified by N2 plasma showed higher NO removal rate than that modified by O2 plasma.
出处
《化工进展》
EI
CAS
CSCD
北大核心
2010年第11期2187-2192,共6页
Chemical Industry and Engineering Progress
基金
国家自然科学基金(20977034)
广州重大科技专项计划(X2DLB2080501)
工业聚集区污染控制与生态修复教育部重点实验室项目
关键词
低温选择性催化还原
介质阻挡放电
低温等离子体
表面改性
活性炭纤维
low-temperature selective catalytic reduction
dielectric barrier discharge
low-temperature plasma
surface modification
activated carbon fiber
