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2,5,8,11-Tetra-Tertbutylperylene作为辅助掺杂剂的红色有机电致发光二极管(英文) 被引量:2

Red Organic Light Emitting Diodes with Assist Dopant 2,5,8,11-Tetra-Tertbutylperylene
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摘要 制备了采用9,10-di-(2-naphthyl)anthracene(ADN)作为主体,4-(dicya-nomethylene)-2-t-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran(DCJTB)作为红色发光中心,2,5,8,11-tetra-tertbutylperylene(TBPe)作为辅助掺杂剂的红光有机电致发光器件。4,4′,4″-tris[2-naphthyl(phenyl)amino]triphenylamine(2TNATA)用作空穴注入材料,4,4′-bis[N-(1-naphthyl)-N-phenylamino]biphenyl(NPB),tris-(8-hydroxyquinoline)aluminum(Alq3)用于空穴和电子传输。实验结果表明,掺有DCJTB的ADN也可实现红色发光,掺入TBPe作为辅助掺杂,可以提高该红光器件的效率,但几乎不改变器件色坐标。此外,2%TBPe(质量分数)作为辅助掺杂的器件表现出最佳的流明效率和最大升温速率。 A red organic light emitting device with host 9,10-di-(2-naphthyl)anthracene (ADN)and red dopant 4-(dicyanomethylene)-2-t-butyl-6(1,1,7,7-tetramethyljulolidyl-9enyl)-4H-pyran(DCJTB)and assist blue dopant 2,5,8,11-tetra-tertbutylperylene(TBPe) was fabricated,and 4,4′,4″-tris[2-naphthyl(phenyl)amino]triphenylamine(2TNATA),4,4'-bis[N-(1-naphthyl)-N-phenylamino]biphenyl(NPB),tris-(8-hydroxyquinoline)aluminum (Alq3)were used as hole injection,hole transportation,electron transportation materials,respectively.The results show that ADN doped with DCJTB can realize red emission as well,and the use of TBPe as assist dopant effectively enhance the device luminous efficiency,yet almost have no effects on CIE coordinates.Additionally,devices with 2% TBPe(mass fraction)appear optimum luminous efficiency and highest temperature increase rate.
作者 蒋谦 张方辉
出处 《液晶与显示》 CAS CSCD 北大核心 2010年第5期666-671,共6页 Chinese Journal of Liquid Crystals and Displays
基金 浙江省温州市科技计划项目(No.H20080004) 陕西省教育厅专项科研项目(No.07JK191) 陕西省13115显示器工程中心建设项目(No.20072DGC-07)
关键词 红色有机电致发光二极管 TBPe DCJTB 效率 温度 red OLEDs; TBPe; DCJTB; efficiency; temperature;
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