摘要
In-situ Raman spectroscopic ts of lawsonite in the OH and H20 stretching region were conducted up to approximately 2.5 GPa and 400 ℃ with a hydrothermal diamondanvil cell. In the experimental design at room temperature, the ratio of band-area and the width at half maximum of the decomposed Raman band shows discontinuities at 0.8 GPa, and correspondingly, the 695-cm1 peak in the low-wavenumber region was split into two peaks. In the experiments at high temperature, the splitting of the 695-cm^-1 peak was induced at 2.4 GPa and 250 ℃ These findings demonstrate the existence of discontinuities in the pressure response of the strength of the hydrogen bonds, which suggests a possible change of the hydrogen-bonded structure in lawsonite under these conditions.
In-situ Raman spectroscopic ts of lawsonite in the OH and H20 stretching region were conducted up to approximately 2.5 GPa and 400 ℃ with a hydrothermal diamondanvil cell. In the experimental design at room temperature, the ratio of band-area and the width at half maximum of the decomposed Raman band shows discontinuities at 0.8 GPa, and correspondingly, the 695-cm1 peak in the low-wavenumber region was split into two peaks. In the experiments at high temperature, the splitting of the 695-cm^-1 peak was induced at 2.4 GPa and 250 ℃ These findings demonstrate the existence of discontinuities in the pressure response of the strength of the hydrogen bonds, which suggests a possible change of the hydrogen-bonded structure in lawsonite under these conditions.
基金
supported by the National Basic Research Pro-gram of China (No. 2009CB825007)
the National Natural Science Foundation of China (Nos. 40730314, 40821002)
