摘要
以十元环大环三胺配体1,4,7-三氮杂环癸烷(tacd)为主配体,分别与钴、镍、铜和锌的顺丁烯二酸盐和己二酸盐进行反应,得到了8种含有双大环的单核配合物,利用元素分析,红外光谱以及热重分析等手段对它们的结构进行了表征.结果表明这八种配合物具有类似的配位结构.
Eight mononuclear transition metal complexes have been obtained through the reaction of maleate and adipate salts of cobalt,nickel,copper and zinc with macrocyclic triamine ligand 1,4,7-triazacyclodecane （tacd）.Structures of the products have been characterized by means of elemental analysis,infrared spectrometr and thermal gravimetric analysis.Results show that the eight complexes have similar composition and coordination structure.
出处
《化学研究》
CAS
2010年第5期14-17,共4页
Chemical Research
基金
陕西省教育厅专项科研计划项目(09JK393)
中药制药重点学科资助课题
关键词
大环三胺
过渡金属
配合物
结构表征
macrocyclic triamine
transition metal
complex
structure characterization
