摘要
以合成具有生物活性的配合物为目的,首次合成了苊醌缩氨基硫脲Pt(II)配合物,通过元素分析、红外光谱、紫外光谱和热重差热分析等对配合物进行了结构表征,结果表明配合物为1:1型的配合物,配体配位过程中N-H上质子脱去,以ONS三齿螯合形式与Pt(II)配位。
In this paper,the platinum(Ⅱ) complex of acenaphthenequinone thiosemicarbazone is synthesized for the first time and its structure is characterized by elemental analysis,IR spectra,UV spectra and thermal analysis.The experimental result indicated that the molar ratio of Pt(Ⅱ) with the ligand is 1:1 and the ligand may act as tridentate ONS donor for Pt(Ⅱ) complex.
出处
《安阳工学院学报》
2010年第4期28-29,43,共3页
Journal of Anyang Institute of Technology