摘要
合成了两种新型的含三甲胺和十八叔胺阳离子基团的螺吡喃染料,采用核磁共振氢谱、质谱、二维谱等手段,对染料及其中间体进行了结构表征。利用紫外—可见光谱研究了化合物的光致变色性。结果表明,含三甲胺阳离子基团的螺吡喃染料具有逆光致变色性和酸致变色性;含十八叔胺阳离子基团的螺吡喃染料仅仅表现出正常的光致变色性。
Two novel spirpoyran dyes containing trimethyl amine and octadecylpropan amine cationic moiety were synthesized.The chemical structures of the dyes and their intermediates were characterized by API-ES-MS,1H-NMR,g-COSY and g-HSQC.The relationship between chemical structures and their photochemical properties were studied with UV-visible spectra.The results showed that spiropyran containing trimethyl amine cationic moiety exhibits negative photochromic properties and acidchromic properties,but the spiropyran containing octadecylpropan amine cationic moiety only presents normal photochromic properties.
出处
《染料与染色》
CAS
2010年第4期4-6,3,共4页
Dyestuffs and Coloration
