摘要
The possibility of direct analytical applications of ferrate（Ⅵ） solution,which was freshly electrogenerated in low-concentration NaOH electrolyte,was studied by a flow-injection-chemiluminescence（FI-CL） system.It was found that some inorganic ions, organic molecule and biomolecule could enhance the chemiluminescence emission caused by ferrate（Ⅵ）-luminol reaction.V（Ⅴ）, Ca（Ⅱ）,Mg（Ⅱ）,phloroglucinol,and bovine hemoglobin（Hb） chosen as samples were successfully detected by this developed method.The analytical characteristics of the system for the analytes determination including linear ranges,correlation coefficients, limits of detection combined with FI analysis were studied.
The possibility of direct analytical applications of ferrate（Ⅵ） solution,which was freshly electrogenerated in low-concentration NaOH electrolyte,was studied by a flow-injection-chemiluminescence（FI-CL） system.It was found that some inorganic ions, organic molecule and biomolecule could enhance the chemiluminescence emission caused by ferrate（Ⅵ）-luminol reaction.V（Ⅴ）, Ca（Ⅱ）,Mg（Ⅱ）,phloroglucinol,and bovine hemoglobin（Hb） chosen as samples were successfully detected by this developed method.The analytical characteristics of the system for the analytes determination including linear ranges,correlation coefficients, limits of detection combined with FI analysis were studied.
基金
supported by the National Natural Science Foundation of China(No.20005005)
Hubei Biomass-Resource Chemistry and Environmental Biotechnology Key Laboratory(Wuhan University)(No. HBRCEBL2007004)
the Opening Foundation of State Key Laboratory of Agricultural Microbiology(No. AML-200905)
